Xenon

Xenon is a chemical element; it has symbol Xe and atomic number 54. It is a dense, colorless, odorless noble gas found in Earth's atmosphere in trace amounts. Although generally unreactive, it can undergo a few chemical reactions such as the formation of xenon hexafluoroplatinate, the first noble gas compound to be synthesized.

Xenon, 54Xe
A xenon-filled discharge tube glowing light blue
Xenon
Pronunciation
  • /ˈzɛnɒn/
    (ZEN-on)
  • /ˈznɒn/
    (ZEE-non)
Appearancecolorless gas, exhibiting a blue glow when placed in an electric field
Standard atomic weight Ar°(Xe)
Xenon in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
Kr

Xe

Rn
iodinexenoncaesium
Atomic number (Z)54
Groupgroup 18 (noble gases)
Periodperiod 5
Block  p-block
Electron configuration[Kr] 4d10 5s2 5p6
Electrons per shell2, 8, 18, 18, 8
Physical properties
Phase at STPgas
Melting point161.40 K (−111.75 °C, −169.15 °F)
Boiling point165.051 K (−108.099 °C, −162.578 °F)
Density (at STP)5.894 g/L
when liquid (at b.p.)2.942 g/cm3
Triple point161.405 K, 81.77 kPa
Critical point289.733 K, 5.842 MPa
Heat of fusion2.27 kJ/mol
Heat of vaporization12.64 kJ/mol
Molar heat capacity21.01 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 83 92 103 117 137 165
Atomic properties
Oxidation states0, +2, +4, +6, +8 (rarely more than 0; a weakly acidic oxide)
ElectronegativityPauling scale: 2.60
Ionization energies
  • 1st: 1170.4 kJ/mol
  • 2nd: 2046.4 kJ/mol
  • 3rd: 3099.4 kJ/mol
Covalent radius140±9 pm
Van der Waals radius216 pm
Spectral lines of xenon
Other properties
Natural occurrenceprimordial
Crystal structure face-centered cubic (fcc)
Thermal conductivity5.65×10−3 W/(m⋅K)
Magnetic orderingdiamagnetic
Molar magnetic susceptibility−43.9×10−6 cm3/mol (298 K)
Speed of soundgas: 178 m·s−1
liquid: 1090 m/s
CAS Number7440-63-3
History
Discovery and first isolationWilliam Ramsay and Morris Travers (1898)
Isotopes of xenon
Main isotopes Decay
abun­dance half-life (t1/2) mode pro­duct
124Xe 0.095% 1.8×1022 y εε 124Te
125Xe synth 16.9 h β+ 125I
126Xe 0.0890% stable
127Xe synth 36.345 d ε 127I
128Xe 1.91% stable
129Xe 26.4% stable
130Xe 4.07% stable
131Xe 21.2% stable
132Xe 26.9% stable
133Xe synth 5.247 d β 133Cs
134Xe 10.4% stable
135Xe synth 9.14 h β 135Cs
136Xe 8.86% 2.165×1021 y ββ 136Ba

Xenon is used in flash lamps and arc lamps, and as a general anesthetic. The first excimer laser design used a xenon dimer molecule (Xe2) as the lasing medium, and the earliest laser designs used xenon flash lamps as pumps. Xenon is also used to search for hypothetical weakly interacting massive particles and as a propellant for ion thrusters in spacecraft.

Naturally occurring xenon consists of seven stable isotopes and two long-lived radioactive isotopes. More than 40 unstable xenon isotopes undergo radioactive decay, and the isotope ratios of xenon are an important tool for studying the early history of the Solar System. Radioactive xenon-135 is produced by beta decay from iodine-135 (a product of nuclear fission), and is the most significant (and unwanted) neutron absorber in nuclear reactors.

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