Radon

Radon is a chemical element; it has symbol Rn and atomic number 86. It is a radioactive noble gas and is colorless and odorless. Of the three naturally occurring radon isotopes, only radon-222 has a sufficiently long half-life (3.825 days) for it to be released from the soil and rock, where it is generated. Radon isotopes are the immediate decay products of radium isotopes. Radon's most stable isotope, radon-222, has a half-life of only 3.8 days, making radon one of the rarest elements. Radon will be present on Earth for several billion more years, despite its half-life being a mere 3.8 days, because it is constantly being produced as a step in the decay chain of uranium-238, and that of thorium-232, each of which is an extremely abundant radioactive nuclide with a half-life of several billion years. The decay of radon produces many other short-lived nuclides, known as "radon daughters", ending at stable isotopes of lead. Radon-222 occurs in significant quantities as a step in the normal radioactive decay chain of uranium-238, also known as the uranium series, which slowly decays into a variety of radioactive nuclides and eventually decays into lead-206, which is stable. Radon-220 occurs in minute quantities as an intermediate step in the decay chain of thorium-232, also known as the thorium series, which eventually decays into lead-208, which is stable.

Radon, 86Rn
Radon
Pronunciation/ˈrdɒn/ (RAY-don)
Appearancecolorless gas
Mass number[222]
Radon in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
Xe

Rn

Og
astatineradonfrancium
Atomic number (Z)86
Groupgroup 18 (noble gases)
Periodperiod 6
Block  p-block
Electron configuration[Xe] 4f14 5d10 6s2 6p6
Electrons per shell2, 8, 18, 32, 18, 8
Physical properties
Phase at STPgas
Melting point202 K (−71 °C, −96 °F)
Boiling point211.5 K (−61.7 °C, −79.1 °F)
Density (at STP)9.73 g/L
when liquid (at b.p.)4.4 g/cm3
Critical point377 K, 6.28 MPa
Heat of fusion3.247 kJ/mol
Heat of vaporization18.10 kJ/mol
Molar heat capacity5R/2 = 20.786 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 110 121 134 152 176 211
Atomic properties
Oxidation states0, +2, +6
ElectronegativityPauling scale: 2.2
Ionization energies
  • 1st: 1037 kJ/mol
Covalent radius150 pm
Van der Waals radius220 pm
Spectral lines of radon
Other properties
Natural occurrencefrom decay
Crystal structure face-centered cubic (fcc)

(predicted)
Thermal conductivity3.61×10−3  W/(m⋅K)
Magnetic orderingnon-magnetic
CAS Number10043-92-2
History
DiscoveryErnest Rutherford and Robert B. Owens (1899)
First isolationWilliam Ramsay and Robert Whytlaw-Gray (1910)
Isotopes of radon
Main isotopes Decay
abun­dance half-life (t1/2) mode pro­duct
210Rn synth 2.4 h α 206Po
211Rn synth 14.6 h ε 211At
α 207Po
222Rn trace 3.8235 d α 218Po
224Rn synth 1.8 h β 224Fr

Under standard conditions, radon is gaseous and can be easily inhaled, posing a health hazard. However, the primary danger comes not from radon itself, but from its decay products, known as radon daughters. These decay products, often existing as single atoms or ions, can attach themselves to airborne dust particles. Although radon is a noble gas and does not adhere to lung tissue, meaning it is often exhaled before decaying, the radon daughters attached to dust are more likely to stick to the lungs. This increases the risk of harm, as the radon daughters can cause damage to lung tissue. Radon and its daughters are, taken together, often the single largest contributor to an individual's background radiation dose, but due to local differences in geology, the level of exposure to radon gas differs from place to place. A common source is uranium-containing minerals in the ground, and therefore it accumulates in subterranean areas such as basements. Radon can also occur in some ground water like spring waters and hot springs. Climate change may cause radon previously trapped underground to be released as permafrost thaws, particularly in areas like the Arctic, Alaska, Canada, Greenland and Russia. It is possible to test for radon in buildings, and to use techniques such as sub-slab depressurization for mitigation.

Epidemiological studies have shown a clear link between breathing high concentrations of radon and incidence of lung cancer. Radon is a contaminant that affects indoor air quality worldwide. According to the United States Environmental Protection Agency (EPA), radon is the second most frequent cause of lung cancer, after cigarette smoking, causing 21,000 lung cancer deaths per year in the United States. About 2,900 of these deaths occur among people who have never smoked. While radon is the second most frequent cause of lung cancer, it is the number one cause among non-smokers, according to EPA policy-oriented estimates. Significant uncertainties exist for the health effects of low-dose exposures.

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