Thulium

Thulium is a chemical element; it has symbol Tm and atomic number 69. It is the thirteenth and third-last element in the lanthanide series. Like the other lanthanides, the most common oxidation state is +3, seen in its oxide, halides and other compounds; however, the +2 oxidation state can also be stable. In aqueous solution, like compounds of other late lanthanides, soluble thulium compounds form coordination complexes with nine water molecules.

Thulium, 69Tm
Thulium
Pronunciation/ˈθjliəm/ (THEW-lee-əm)
Appearancesilvery gray
Standard atomic weight Ar°(Tm)
  • 168.934219±0.000005
  • 168.93±0.01 (abridged)
Thulium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson


Tm

Md
erbiumthuliumytterbium
Atomic number (Z)69
Groupf-block groups (no number)
Periodperiod 6
Block  f-block
Electron configuration[Xe] 4f13 6s2
Electrons per shell2, 8, 18, 31, 8, 2
Physical properties
Phase at STPsolid
Melting point1818 K (1545 °C, 2813 °F)
Boiling point2223 K (1950 °C, 3542 °F)
Density (near r.t.)9.32 g/cm3
when liquid (at m.p.)8.56 g/cm3
Heat of fusion16.84 kJ/mol
Heat of vaporization191 kJ/mol
Molar heat capacity27.03 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 1117 1235 1381 1570 (1821) (2217)
Atomic properties
Oxidation states0, +1, +2, +3 (a basic oxide)
ElectronegativityPauling scale: 1.25
Ionization energies
  • 1st: 596.7 kJ/mol
  • 2nd: 1160 kJ/mol
  • 3rd: 2285 kJ/mol
Atomic radiusempirical: 176 pm
Covalent radius190±10 pm
Spectral lines of thulium
Other properties
Natural occurrenceprimordial
Crystal structure hexagonal close-packed (hcp)
Thermal expansionpoly: 13.3 µm/(m⋅K) (at r.t.)
Thermal conductivity16.9 W/(m⋅K)
Electrical resistivitypoly: 676 nΩ⋅m (at r.t.)
Magnetic orderingparamagnetic (at 300 K)
Molar magnetic susceptibility+25500×10−6 cm3/mol (291 K)
Young's modulus74.0 GPa
Shear modulus30.5 GPa
Bulk modulus44.5 GPa
Poisson ratio0.213
Vickers hardness470–650 MPa
Brinell hardness470–900 MPa
CAS Number7440-30-4
History
Namingafter Thule, a mythical region in Scandinavia
Discovery and first isolationPer Teodor Cleve (1879)
Isotopes of thulium
Main isotopes Decay
abun­dance half-life (t1/2) mode pro­duct
167Tm synth 9.25 d ε 167Er
168Tm synth 93.1 d β+ 168Er
169Tm 100% stable
170Tm synth 128.6 d β 170Yb
171Tm synth 1.92 y β 171Yb

In 1879, the Swedish chemist Per Teodor Cleve separated from the rare earth oxide erbia another two previously unknown components, which he called holmia and thulia; these were the oxides of holmium and thulium, respectively. A relatively pure sample of thulium metal was first obtained in 1911.

Thulium is the second-least abundant of the lanthanides, after radioactively unstable promethium which is only found in trace quantities on Earth. It is an easily workable metal with a bright silvery-gray luster. It is fairly soft and slowly tarnishes in air. Despite its high price and rarity, thulium is used as the radiation source in portable X-ray devices, and in some solid-state lasers. It has no significant biological role and is not particularly toxic.

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