Potassium chloride

Potassium chloride (KCl, or potassium salt) is a metal halide salt composed of potassium and chlorine. It is odorless and has a white or colorless vitreous crystal appearance. The solid dissolves readily in water, and its solutions have a salt-like taste. Potassium chloride can be obtained from ancient dried lake deposits. KCl is used as a fertilizer, in medicine, in scientific applications, domestic water softeners (as a substitute for sodium chloride salt), and in food processing, where it may be known as E number additive E508.

Potassium chloride
Names
Other names
Sylvite
Muriate of potash
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
DrugBank
ECHA InfoCard 100.028.374
E number E508 (acidity regulators, ...)
KEGG
RTECS number
  • TS8050000
UNII
  • InChI=1S/ClH.K/h1H;/q;+1/p-1 Y
    Key: WCUXLLCKKVVCTQ-UHFFFAOYSA-M Y
  • InChI=1/ClH.K/h1H;/q;+1/p-1
    Key: WCUXLLCKKVVCTQ-REWHXWOFAZ
  • [Cl-].[K+]
Properties
KCl
Molar mass 74.555 g·mol−1
Appearance white crystalline solid
Odor odorless
Density 1.984 g/cm3
Melting point 770 °C (1,420 °F; 1,040 K)
Boiling point 1,420 °C (2,590 °F; 1,690 K)
27.77 g/100mL (0 °C)
33.97 g/100mL (20 °C)
54.02 g/100mL (100 °C)
Solubility Soluble in glycerol, alkalies
Slightly soluble in alcohol Insoluble in ether
Solubility in ethanol 0.288 g/L (25 °C)
Acidity (pKa) ~7
39.0·10−6 cm3/mol
1.4902 (589 nm)
Structure
face centered cubic
Fm3m, No. 225
a = 629.2 pm
Octahedral (K+)
Octahedral (Cl)
Thermochemistry
83 J·mol−1·K−1
−436 kJ·mol−1
Pharmacology
A12BA01 (WHO) B05XA01 (WHO)
Oral, IV, IM
Pharmacokinetics:
Kidney: 90%; Fecal: 10%
Hazards
NFPA 704 (fire diamond)
1
0
0
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
2600 mg/kg (oral, rat)
Safety data sheet (SDS) ICSC 1450
Related compounds
Other anions
Potassium fluoride
Potassium bromide
Potassium iodide
Other cations
Lithium chloride
Sodium chloride
Rubidium chloride
Caesium chloride
Ammonium chloride
Related compounds
Potassium hypochlorite
Potassium chlorite
Potassium chlorate
Potassium perchlorate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

It occurs naturally as the mineral sylvite, which is named after salt's historical designations sal degistivum Sylvii and sal febrifugum Sylvii, and in combination with sodium chloride as sylvinite.

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