Potassium perchlorate

Potassium perchlorate is the inorganic salt with the chemical formula KClO4. Like other perchlorates, this salt is a strong oxidizer although it usually reacts very slowly with organic substances. This, usually obtained as a colorless, crystalline solid, is a common oxidizer used in fireworks, ammunition percussion caps, explosive primers, and is used variously in propellants, flash compositions, stars, and sparklers. It has been used as a solid rocket propellant, although in that application it has mostly been replaced by the higher performance ammonium perchlorate.

Potassium perchlorate
Names
Other names
Potassium chlorate(VII); Perchloric acid, potassium salt; peroidin
Identifiers
3D model (JSmol)
ChEMBL
ChemSpider
ECHA InfoCard 100.029.011
EC Number
  • 231-912-9
RTECS number
  • SC9700000
UNII
UN number 1489
  • InChI=1S/ClHO4.K/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1 Y
    Key: YLMGFJXSLBMXHK-UHFFFAOYSA-M Y
  • InChI=1/ClHO4.K/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1
    Key: YLMGFJXSLBMXHK-REWHXWOFAB
  • [K+].[O-]Cl(=O)(=O)=O
Properties
KClO4
Molar mass 138.55 g/mol
Appearance colourless/ white crystalline powder
Density 2.5239 g/cm3
Melting point 610 °C (1,130 °F; 883 K)
decomposes from 400 °C
0.76 g/100 mL (0 °C)
1.5 g/100 mL (25 °C)
4.76 g/100 mL (40 °C)
21.08 g/100 mL (100 °C)
1.05·10−2
Solubility negligible in alcohol
insoluble in ether
Solubility in ethanol 47 mg/kg (0 °C)
120 mg/kg (25 °C)
Solubility in acetone 1.6 g/kg
Solubility in ethyl acetate 15 mg/kg
1.4724
Structure
Rhombohedral
Thermochemistry
111.35 J/mol·K
150.86 J/mol·K
-433 kJ/mol
-300.4 kJ/mol
Hazards
GHS labelling:
Danger
H271, H302, H335
P220, P280
NFPA 704 (fire diamond)
Safety data sheet (SDS) MSDS
Related compounds
Other anions
Potassium chloride
Potassium chlorate
Potassium periodate
Other cations
Ammonium perchlorate
Sodium perchlorate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references
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