Germanium disulfide

Germanium disulfide or Germanium(IV) sulfide is the inorganic compound with the formula GeS2. It is a white high-melting crystalline solid. The compound is a 3-dimensional polymer, in contrast to silicon disulfide, which is a one-dimensional polymer. The Ge-S distance is 2.19 Å.

Germanium disulfide
Names
Systematic IUPAC name
Germanium(IV) sulfide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.031.537
EC Number
  • 234-705-1
  • InChI=1S/GeS2/c2-1-3 Y
    Key: YIZVROFXIVWAAZ-UHFFFAOYSA-N Y
  • InChI=1/GeS2/c2-1-3
    Key: YIZVROFXIVWAAZ-UHFFFAOYAU
  • S=[Ge]=S
Properties
GeS2
Molar mass 136.75 g·mol−1
Appearance White, translucent crystals
Density 2.94 g cm−3
Melting point 840 °C (1,540 °F; 1,110 K)
Boiling point 1,530 °C (2,790 °F; 1,800 K)
0.45 g/100 mL
Solubility soluble in liquid ammonia
53.3·10−6 cm3/mol
Structure
monoclinic, mP36
Pc, No. 7
tetrahedral at Ge, bent at S
Thermochemistry
50 J /(mol K)
-150.06 kJ/mol
Related compounds
Related compounds
Carbon disulfide

Germanium dioxide
Germanium diselenide
Germanium monosulfide
Lead disulfide
Silicon sulfide
Tin disulfide

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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