Germanium dioxide

Germanium dioxide, also called germanium(IV) oxide, germania, and salt of germanium, is an inorganic compound with the chemical formula GeO2. It is the main commercial source of germanium. It also forms as a passivation layer on pure germanium in contact with atmospheric oxygen.

Germanium dioxide
Tetragonal rutile form
Names
IUPAC name
Germanium dioxide
Other names
Germanium(IV) oxide
Germania
ACC10380
G-15
Neutral germanium oxide (1:2)
Germanic oxide
Salt of germanium
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.013.801
RTECS number
  • LY5240000
UNII
  • InChI=1S/GeO2/c2-1-3 Y
    Key: YBMRDBCBODYGJE-UHFFFAOYSA-N Y
  • InChI=1/GeO2/c2-1-3
    Key: YBMRDBCBODYGJE-UHFFFAOYAG
  • O=[Ge]=O
Properties
GeO2
Molar mass 104.6388 g/mol
Appearance White powder or colourless crystals
Density 4.228 g/cm3
Melting point 1,115 °C (2,039 °F; 1,388 K)
4.47 g/L (25 °C)
10.7 g/L (100 °C)
Solubility Soluble in HF,
insoluble in other acid. Soluble in strong alkaline conditions.
34.3·10−6 cm3/mol
1.650
Structure
Hexagonal
Hazards
NFPA 704 (fire diamond)
1
0
0
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
3700 mg/kg (rat, oral)
Related compounds
Other anions
Germanium disulfide
Germanium diselenide
Other cations
Carbon dioxide
Silicon dioxide
Tin dioxide
Lead dioxide
Related compounds
Germanium monoxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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