Tin(IV) sulfide
Tin(IV) sulfide is a compound with the formula SnS
2. The compound crystallizes in the cadmium iodide motif, with the Sn(IV) situated in "octahedral holes' defined by six sulfide centers. It occurs naturally as the rare mineral berndtite. It is useful as semiconductor material with band gap 2.2 eV.
Names | |
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IUPAC name
Tin(IV) sulfide | |
Other names
Tin disulfide, Stannic sulfide, Mosaic gold | |
Identifiers | |
3D model (JSmol) |
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ChEBI | |
ECHA InfoCard | 100.013.867 |
EC Number |
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PubChem CID |
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UNII | |
CompTox Dashboard (EPA) |
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Properties | |
S2Sn | |
Molar mass | 182.83 g·mol−1 |
Appearance | Gold-yellow powder |
Odor | Odorless |
Density | 4.5 g/cm3 |
Melting point | 600 °C (1,112 °F; 873 K) decomposes |
Insoluble | |
Solubility | Soluble in aq. alkalis, decompose in aqua regia Insoluble in alkyl acetates, acetone |
Structure | |
Rhombohedral, hP3 | |
P3m1, No. 164 | |
3 2/m | |
a = 3.65 Å, c = 5.88 Å α = 90°, β = 90°, γ = 120° | |
Octahedral (Sn4+) | |
Hazards | |
GHS labelling: | |
Warning | |
H302, H312, H315, H319, H332, H335 | |
P261, P280, P301+P312, P302+P352, P304+P340, P305+P351+P338, P332+P313 | |
NFPA 704 (fire diamond) | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references |
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