Tin(IV) sulfide

Tin(IV) sulfide is a compound with the formula SnS
2
. The compound crystallizes in the cadmium iodide motif, with the Sn(IV) situated in "octahedral holes' defined by six sulfide centers. It occurs naturally as the rare mineral berndtite. It is useful as semiconductor material with band gap 2.2 eV.

Tin(IV) sulfide
Names
IUPAC name
Tin(IV) sulfide
Other names
Tin disulfide, Stannic sulfide, Mosaic gold
Identifiers
3D model (JSmol)
ChEBI
ECHA InfoCard 100.013.867
EC Number
  • 215-252-9
UNII
  • InChI=1S/2S.Sn/q2*-2;+4 N[inchi]
    Key: TUTLDIXHQPSHHQ-UHFFFAOYSA-N N[inchi]
  • [S-2].[S-2].[Sn+4]
  • (S=Sn=S): S=[Sn]=S
Properties
S2Sn
Molar mass 182.83 g·mol−1
Appearance Gold-yellow powder
Odor Odorless
Density 4.5 g/cm3
Melting point 600 °C (1,112 °F; 873 K)
decomposes
Insoluble
Solubility Soluble in aq. alkalis, decompose in aqua regia
Insoluble in alkyl acetates, acetone
Structure
Rhombohedral, hP3
P3m1, No. 164
3 2/m
a = 3.65 Å, c = 5.88 Å
α = 90°, β = 90°, γ = 120°
Octahedral (Sn4+)
Hazards
GHS labelling:
Warning
H302, H312, H315, H319, H332, H335
P261, P280, P301+P312, P302+P352, P304+P340, P305+P351+P338, P332+P313
NFPA 704 (fire diamond)
1
0
0
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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