Copper(II) hydroxide

Copper(II) hydroxide is the hydroxide of copper with the chemical formula of Cu(OH)2. It is a pale greenish blue or bluish green solid. Some forms of copper(II) hydroxide are sold as "stabilized" copper(II) hydroxide, although they likely consist of a mixture of copper(II) carbonate and hydroxide. Cupric hydroxide is a strong base, although its low solubility in water makes this hard to observe directly.

Copper(II) hydroxide
Names
IUPAC name
Copper(II) hydroxide
Other names
Cupric hydroxide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.039.817
KEGG
UNII
  • InChI=1S/Cu.2H2O/h;2*1H2/q+2;;/p-2 Y
    Key: JJLJMEJHUUYSSY-UHFFFAOYSA-L Y
  • InChI=1/Cu.2H2O/h;2*1H2/q+2;;/p-2
    Key: JJLJMEJHUUYSSY-NUQVWONBAH
  • [Cu+2].[OH-].[OH-]
Properties
Cu(OH)2
Molar mass 97.561 g/mol
Appearance Blue or blue-green solid
Density 3.368 g/cm3, solid
Melting point 80 °C (176 °F; 353 K) approximate, decomposes into CuO
negligible
2.20 x 10−20
Solubility insoluble in ethanol;
soluble in NH4OH
+1170.0·10−6 cm3/mol
Thermochemistry
108 J·mol−1·K−1
−450 kJ·mol−1
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Skin, Eye, & Respiratory Irritant
NFPA 704 (fire diamond)
2
0
0
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
1000 mg/kg (oral, rat)
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 1 mg/m3 (as Cu)
REL (Recommended)
TWA 1 mg/m3 (as Cu)
IDLH (Immediate danger)
TWA 100 mg/m3 (as Cu)
Safety data sheet (SDS) SDS
Related compounds
Other anions
Copper(II) oxide
Copper(II) carbonate
Copper(II) sulfate
Copper(II) chloride
Other cations
Nickel(II) hydroxide
Zinc hydroxide
Iron(II) hydroxide
Cobalt hydroxide
Related compounds
Copper(I) oxide
Copper(I) chloride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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