Copper(I) oxide

Copper(I) oxide or cuprous oxide is the inorganic compound with the formula Cu2O. It is one of the principal oxides of copper, the other being copper(II) oxide or cupric oxide (CuO). Cuprous oxide is a red-coloured solid and is a component of some antifouling paints. The compound can appear either yellow or red, depending on the size of the particles. Copper(I) oxide is found as the reddish mineral cuprite.

Copper(I) oxide


Names
IUPAC name
Copper(I) oxide
Other names
Cuprous oxide
Dicopper oxide
Cuprite
Red copper oxide
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.013.883
EC Number
  • 215-270-7
KEGG
RTECS number
  • GL8050000
UNII
  • InChI=1S/2Cu.O/q2*+1;-2 Y
    Key: KRFJLUBVMFXRPN-UHFFFAOYSA-N Y
  • InChI=1/2Cu.O/rCu2O/c1-3-2
    Key: BERDEBHAJNAUOM-YQWGQOGZAF
  • InChI=1/2Cu.O/q2*+1;-2
    Key: KRFJLUBVMFXRPN-UHFFFAOYAM
  • [Cu]O[Cu]
  • [Cu+].[Cu+].[O-2]
Properties
Cu2O
Molar mass 143.09 g/mol
Appearance brownish-red solid
Density 6.0 g/cm3
Melting point 1,232 °C (2,250 °F; 1,505 K)
Boiling point 1,800 °C (3,270 °F; 2,070 K)
Insoluble
Solubility in acid Soluble
Band gap 2.137 eV
−20×10−6 cm3/mol
Structure
cubic
Pn3m, #224
a = 4.2696
Thermochemistry
93 J·mol−1·K−1
−170 kJ·mol−1
Hazards
GHS labelling:
Danger
H302, H318, H332, H410
P273, P305+P351+P338
NFPA 704 (fire diamond)
2
0
1
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 1 mg/m3 (as Cu)
REL (Recommended)
TWA 1 mg/m3 (as Cu)
IDLH (Immediate danger)
TWA 100 mg/m3 (as Cu)
Safety data sheet (SDS) SIRI.org
Related compounds
Other anions
Copper(I) sulfide
Copper(II) sulfide
Copper(I) selenide
Other cations
Copper(II) oxide
Silver(I) oxide
Nickel(II) oxide
Zinc oxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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