Nickel(II) hydroxide

Nickel(II) hydroxide is the inorganic compound with the formula Ni(OH)2. It is a lime-green solid that dissolves with decomposition in ammonia and amines and is attacked by acids. It is electroactive, being converted to the Ni(III) oxy-hydroxide, leading to widespread applications in rechargeable batteries.

Nickel(II) hydroxide
Names
IUPAC name
Nickel(II) hydroxide
Other names
Nickel hydroxide, Theophrastite
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.031.813
EC Number
  • 235-008-5
RTECS number
  • QR648000
UNII
  • InChI=1S/Ni.2H2O/h;2*1H2/q+2;;/p-2 Y
    Key: BFDHFSHZJLFAMC-UHFFFAOYSA-L Y
  • InChI=1/Ni.2H2O/h;2*1H2/q+2;;/p-2
    Key: BFDHFSHZJLFAMC-NUQVWONBAJ
  • [Ni+2].[OH-].[OH-]
Properties
Ni(OH)2
Molar mass 92.724 g/mol (anhydrous)
110.72 g/mol (monohydrate)
Appearance green crystals
Density 4.10 g/cm3
Melting point 230 °C (446 °F; 503 K) (anhydrous, decomposes)
0.0015 g/L
5.48×1016
+4500.0·10−6 cm3/mol
Structure
hexagonal, hP3
P3m1, No. 164
a = 0.3117 nm, b = 0.3117 nm, c = 0.4595 nm
α = 90°, β = 90°, γ = 120°
Thermochemistry
79 J·mol−1·K−1
−538 kJ·mol−1
Hazards
GHS labelling:
Danger
H302, H315, H317, H332, H334, H341, H350, H360, H372
P201, P260, P280, P284, P405, P501
Lethal dose or concentration (LD, LC):
1515 mg/kg (oral, rat)
Safety data sheet (SDS) External SDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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