2-Chloroethanol

2-Chloroethanol (also called ethylene chlorohydrin or glycol chlorohydrin) is an organic chemical compound with the chemical formula HOCH2CH2Cl and the simplest beta-halohydrin (chlorohydrin). This colorless liquid has a pleasant ether-like odor. It is miscible with water. The molecule is bifunctional, consisting of both an alkyl chloride and an alcohol functional group.

2-Chloroethanol
Names
Preferred IUPAC name
2-Chloroethan-1-ol
Other names
  • 2-Chloroethanol
  • beta-Chloroethanol
  • 2-Chloro-1-ethanol
  • β-Chloroethanol
  • δ-Chloroethanol
  • 2-Chloroethyl alcohol
  • Ethyl chlorhydrin
  • Ethylene chlorohydrin
  • Glycol chlorohydrin
  • Glycol monochlorohydrin
  • 2-Hydroxyethyl chloride
  • β-Hydroxyethyl chloride
  • 2-Monochloroethanol
Identifiers
3D model (JSmol)
3DMet
878139
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.003.146
EC Number
  • 203-459-7
25389
KEGG
MeSH Ethylene+Chlorohydrin
RTECS number
  • KK0875000
UNII
UN number 1135
  • InChI=1S/C2H5ClO/c3-1-2-4/h4H,1-2H2 Y
    Key: SZIFAVKTNFCBPC-UHFFFAOYSA-N Y
  • OCCCl
Properties
C2H5ClO
Molar mass 80.51 g·mol−1
Appearance Colourless liquid
Odor ether-like
Density 1.201 g/mL
Melting point −62.60 °C; −80.68 °F; 210.55 K
Boiling point 127–131 °C; 260–268 °F; 400–404 K
Miscible
log P −0.107
Vapor pressure 700 Pa (at 20 °C)
1.441
Thermochemistry
−1.1914 MJ/mol
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Highly toxic and flammable
GHS labelling:
Danger
H226, H300+H310+H330
P260, P280, P284, P301+P310, P302+P350
NFPA 704 (fire diamond)
4
2
0
Flash point 55 °C (131 °F; 328 K)
425 °C (797 °F; 698 K)
Explosive limits 5–16%
Lethal dose or concentration (LD, LC):
  • 67 mg/kg (dermal, rabbit)
  • 72 mg/kg (rat, oral)
  • 81 mg/kg (mouse, oral)
  • 71 mg/kg (rat, oral)
  • 110 mg/kg (guinea pig, oral)
  • 7.5 ppm (rat, 1 h)
  • 32 ppm (rat, 4 h)
  • 260 ppm (guinea pig)
  • 33 ppm (rat, 4 h)
  • 87 ppm (rat)
  • 115 ppm (mouse)
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 5 ppm (16 mg/m3) [skin]
REL (Recommended)
C 1 ppm (3 mg/m3) [skin]
IDLH (Immediate danger)
7 ppm
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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