A Captive Network is generally a Wifi one. Such a network redirect any traffic to a local machine. It disallows surfing the Internet, until you have authenticated or accepted ToS.
A captive portal is a special web page that is shown before using the Internet normally. The portal is often used to present a login page.[1] This is done by intercepting most packets, regardless of address or port, until the user opens a browser and tries to access the web. At that time the browser is redirected to a web page which may require authentication and/or payment, or simply display an acceptable use policy and require the user to agree. Captive portals are used at many Wi-Fi hotspots, and can be used to control wired access (e.g. apartment houses, hotel rooms, business centers, "open" Ethernet jacks) as well.