Hope this helps : I have used eventrigger for Loaded event.
Using PlaneProjection :
I am using RotationX which rotates the images around the x-axis of rotation.
<Grid >
<Grid.Triggers>
<EventTrigger>
<BeginStoryboard>
<Storyboard>
<DoubleAnimationUsingKeyFrames Storyboard.TargetProperty="(UIElement.Projection).(PlaneProjection.RotationX)" Storyboard.TargetName="Flip1">
<EasingDoubleKeyFrame KeyTime="0:0:0.3" Value="90.0146"/>
<EasingDoubleKeyFrame KeyTime="0:0:0.6" Value="180"/>
</DoubleAnimationUsingKeyFrames>
<DoubleAnimationUsingKeyFrames Storyboard.TargetProperty="(UIElement.Projection).(PlaneProjection.RotationX)" Storyboard.TargetName="Flip2">
<EasingDoubleKeyFrame KeyTime="0" Value="-180"/>
<EasingDoubleKeyFrame KeyTime="0:0:0.3" Value="-90"/>
<EasingDoubleKeyFrame KeyTime="0:0:0.6" Value="0"/>
</DoubleAnimationUsingKeyFrames>
<ObjectAnimationUsingKeyFrames Storyboard.TargetProperty="(UIElement.Visibility)" Storyboard.TargetName="Flip1">
<DiscreteObjectKeyFrame KeyTime="0">
<DiscreteObjectKeyFrame.Value>
<Visibility>Visible</Visibility>
</DiscreteObjectKeyFrame.Value>
</DiscreteObjectKeyFrame>
<DiscreteObjectKeyFrame KeyTime="0:0:0.3">
<DiscreteObjectKeyFrame.Value>
<Visibility>Collapsed</Visibility>
</DiscreteObjectKeyFrame.Value>
</DiscreteObjectKeyFrame>
</ObjectAnimationUsingKeyFrames>
<ObjectAnimationUsingKeyFrames Storyboard.TargetProperty="(UIElement.Visibility)" Storyboard.TargetName="Flip2">
<DiscreteObjectKeyFrame KeyTime="0">
<DiscreteObjectKeyFrame.Value>
<Visibility>Visible</Visibility>
</DiscreteObjectKeyFrame.Value>
</DiscreteObjectKeyFrame>
<DiscreteObjectKeyFrame KeyTime="0:0:0.3">
<DiscreteObjectKeyFrame.Value>
<Visibility>Visible</Visibility>
</DiscreteObjectKeyFrame.Value>
</DiscreteObjectKeyFrame>
</ObjectAnimationUsingKeyFrames>
</Storyboard>
</BeginStoryboard>
</EventTrigger>
</Grid.Triggers>
<Rectangle x:Name="Flip1" Fill="Aqua" Height="50" Width="50">
<Rectangle.Projection>
<PlaneProjection x:Name="PlaneProjection1"></PlaneProjection>
</Rectangle.Projection>
</Rectangle>
<Rectangle x:Name="Flip2" Fill="Aqua" Height="50" Width="50">
<Rectangle.Projection>
<PlaneProjection x:Name="PlaneProjection2"></PlaneProjection>
</Rectangle.Projection>
</Rectangle>
</Grid>
Using ScaleTransform : Changing horizontal scale from 1 to -1 has the same rotating effect and you can animate ScaleX property to get rotating effect. You should also change it's Visibility from Visible to Hidden and vice versa. To make image disappearing after rotating 90 degrees.
<Rectangle x:Name="Flip3" Fill="Red" Height="50" RenderTransformOrigin="0.5,.5" Width="50">
<Rectangle.RenderTransform>
<ScaleTransform x:Name="st" ScaleX="1" ScaleY="0.1"></ScaleTransform>
</Rectangle.RenderTransform>
<Rectangle.Triggers>
<EventTrigger>
<BeginStoryboard>
<Storyboard>
<DoubleAnimation Storyboard.TargetProperty="(UIElement.RenderTransform).(ScaleTransform.ScaleY)" Storyboard.TargetName="Flip3" From="1" To="-1" Duration="0:0:0.5">
<DoubleAnimation.EasingFunction>
<ExponentialEase EasingMode="EaseOut"></ExponentialEase>
</DoubleAnimation.EasingFunction>
</DoubleAnimation>
</Storyboard>
</BeginStoryboard>
</EventTrigger>
</Rectangle.Triggers>
</Rectangle>