Xenon tetrafluoride

Xenon tetrafluoride is a chemical compound with chemical formula XeF
4
. It was the first discovered binary compound of a noble gas. It is produced by the chemical reaction of xenon with fluorine:

Xe + 2 F
2
XeF
4
Xenon tetrafluoride
Names
IUPAC name
Xenon tetrafluoride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.858
UNII
  • InChI=1S/F4Xe/c1-5(2,3)4 Y
    Key: RPSSQXXJRBEGEE-UHFFFAOYSA-N Y
  • InChI=1/F4Xe/c1-5(2,3)4
    Key: RPSSQXXJRBEGEE-UHFFFAOYAW
  • F[Xe](F)(F)F
Properties
XeF
4
Molar mass 207.2836 g mol−1
Appearance White solid
Density 4.040 g cm−3, solid
Melting point 117 °C (243 °F; 390 K) sublimes
Reacts
Structure
D4h
square planar
0 D
Thermochemistry
146 J·mol−1·K−1
−251 kJ·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

This reaction is exothermic, releasing an energy of 251 kJ/mol.

Xenon tetrafluoride is a colorless crystalline solid that sublimes at 117 °C. Its structure was determined by both NMR spectroscopy and X-ray crystallography in 1963. The structure is square planar, as has been confirmed by neutron diffraction studies. According to VSEPR theory, in addition to four fluoride ligands, the xenon center has two lone pairs of electrons. These lone pairs are mutually trans.

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