Uranium hexafluoride

Uranium hexafluoride, sometimes called hex, is an inorganic compound with the formula UF6. Uranium hexafluoride is a volatile white solid that reacts with water, releasing corrosive hydrofluoric acid. The compound reacts mildly with aluminium, forming a thin surface layer of AlF3 that resists any further reaction from the compound. UF6 is used in the process of enriching uranium, which produces fuel for nuclear reactors and nuclear weapons.

Uranium hexafluoride
Names
IUPAC names
Uranium hexafluoride
Uranium(VI) fluoride
Identifiers
3D model (JSmol)
Abbreviations hex
ChEBI
ChemSpider
ECHA InfoCard 100.029.116
EC Number
  • 232-028-6
2923
RTECS number
  • YR4720000
UNII
UN number 2978 (<1% 235U)
2977 (>1% 235U)
  • InChI=1S/6FH.U/h6*1H;/q;;;;;;+6/p-6 Y
    Key: SANRKQGLYCLAFE-UHFFFAOYSA-H Y
  • InChI=1/6FH.U/h6*1H;/q;;;;;;+6/p-6/rF6U/c1-7(2,3,4,5)6
    Key: SANRKQGLYCLAFE-IIYYNVFAAT
  • F[U](F)(F)(F)(F)F
Properties
UF6
Molar mass 352.02 g/mol
Appearance Colorless solid
Density 5.09 g/cm3, solid
Boiling point 56.5 °C (133.7 °F; 329.6 K) (sublimes, at atmospheric pressure)
Hydrolyzes
Solubility
Structure
Orthorhombic, oP28
Pnma, No. 62
Octahedral (Oh)
0
Thermochemistry
  • Solid, 227.8±1.3 J·K−1·mol−1
  • Gaseous, 377.8±1.3 J·K−1·mol−1
  • Solid, −2197.7±1.8 kJ·mol−1
  • Gaseous, −2148.1±1.8 kJ·mol−1
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Toxic, corrosive, radioactive
GHS labelling:
Danger
H300, H330, H373, H411
NFPA 704 (fire diamond)
Flash point Non-flammable
Safety data sheet (SDS) ICSC 1250
Related compounds
Other anions
Uranium hexachloride
Other cations
Related uranium fluorides
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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