Tungsten hexacarbonyl

Tungsten hexacarbonyl (also called tungsten carbonyl) is an organometallic compound with the formula W(CO)6. This complex gave rise to the first example of a dihydrogen complex.

Tungsten hexacarbonyl
Names
IUPAC name
Hexacarbonyltungsten
Other names
Tungsten carbonyl
Hexacarbonylwolfram
Identifiers
3D model (JSmol)
ECHA InfoCard 100.034.423
EC Number
  • 237-880-2
  • InChI=1/6CO.W/c6*1-2;
  • O=C=[W](=C=O)(=C=O)(=C=O)(=C=O)=C=O
Properties
C6O6W
Molar mass 351.901 g/mol
Appearance Colorless solid
Density 2.65 g/cm3
Melting point 170 °C (338 °F; 443 K) (decomposes)
insoluble
Solubility sparingly in THF
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Flammable, CO source
Hazards
NFPA 704 (fire diamond)
2
0
0
Safety data sheet (SDS) External SDS
Related compounds
Other cations
Chromium hexacarbonyl
Molybdenum hexacarbonyl


Seaborgium hexacarbonyl

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Like its chromium and molybdenum analogs, this colorless compound is noteworthy as a volatile, air-stable derivative of tungsten in its zero oxidation state.

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