Trichloroethylene

Trichloroethylene (TCE) is a halocarbon with the formula C2HCl3, commonly used as an industrial degreasing solvent. It is a clear, colourless, non-flammable, volatile liquid with a chloroform-like pleasant mild smell and sweet taste. Its IUPAC name is trichloroethene. Trichloroethylene has been sold under a variety of trade names. Industrial abbreviations include TCE, trichlor, Trike, Tricky and tri. Under the trade names Trimar and Trilene, it was used as a volatile anesthetic and as an inhaled obstetrical analgesic. It should not be confused with the similar 1,1,1-trichloroethane, which is commonly known as chlorothene.

Trichloroethylene

sample of Trichloroethylene
Names
Preferred IUPAC name
Trichloroethene
Other names
1-Chloro-2,2-Dichloroethylene; 1,1-Dichloro-2-Chloroethylene; Acetylene Trichloride; Anamenth; HCC-1120; TCE; Trethylene; Triclene; Tri; Trico; Trilene; Trimar
Identifiers
3D model (JSmol)
Abbreviations TCE
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.001.062
EC Number
  • 201-167-4
KEGG
RTECS number
  • KX4550000
UNII
UN number 1710
  • InChI=1S/C2HCl3/c3-1-2(4)5/h1H Y
    Key: XSTXAVWGXDQKEL-UHFFFAOYSA-N Y
  • InChI=1/C2HCl3/c3-1-2(4)5/h1H
  • Cl\C=C(/Cl)Cl
  • Cl\C=C(/Cl)Cl
  • ClC=C(Cl)Cl
Properties
C2HCl3
Molar mass 131.38 g·mol−1
Appearance Colorless liquid
Odor pleasant, chloroform-like
Density 1.46 g/cm3 at 20 °C
Melting point −84.8 °C (−120.6 °F; 188.3 K)
Boiling point 86.7 °C (188.1 °F; 359.8 K)
1.280 g/L
Solubility Ether, ethanol, chloroform
log P 2.26
Vapor pressure 58 mmHg (0.076 atm) at 20 °C
−65.8·10−6 cm3/mol
1.4777 at 19.8 °C
Viscosity 0.532 mPa·s
Pharmacology
N01AB05 (WHO)
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Acute exposure can cause dizziness and loss of consciousness, chronic exposure can increase cancer risk. Unstable in presence of light.
GHS labelling:
NFPA 704 (fire diamond)
2
1
0
420 °C (788 °F; 693 K)
Explosive limits 8-10.5%
Lethal dose or concentration (LD, LC):
4920 mg/kg (oral, rat), 29000 mg/kg (dermal, rabbit)
8450 ppm (mouse, 4 hr)
26300 (rat, 1 hr)
2900 ppm (human)
37,200 ppm (guinea pig, 40 min)
5952 ppm (cat, 2 hr)
8000 ppm (rat, 4 hr)
11,000 (rabbit)
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 100 ppm C 200 ppm 300 ppm (5-minute maximum peak in any 2 hours)
REL (Recommended)
Ca
IDLH (Immediate danger)
Ca [1000 ppm]
Safety data sheet (SDS) Mallinckrodt Baker
Legal status
  • BR: Class B1 (Psychoactive drugs)
  • US: banned for medical use (1977)
Related compounds
Vinyl chloride
Tetrachloroethylene
Related compounds
Chloroform
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Supplementary data page
Trichloroethylene (data page)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

TCE is classified as a volatile organic compound.

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