Cadmium iodide

Cadmium iodide is the inorganic compound with the formula CdI2. It is a white hygroscopic solid. It also can be obtained as a mono- and tetrahydrate. It has few applications. It is notable for its crystal structure, which is typical for compounds of the form MX2 with strong polarization effects.

Cadmium iodide
Names
IUPAC name
Cadmium(II) iodide
Other names
Cadmium diiodide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.294
EC Number
  • 232-223-6
UNII
  • InChI=1S/Cd.2HI/h;2*1H/q+2;;/p-2 Y
    Key: OKIIEJOIXGHUKX-UHFFFAOYSA-L Y
  • InChI=1/Cd.2HI/h;2*1H/q+2;;/p-2
    Key: OKIIEJOIXGHUKX-NUQVWONBAZ
  • [Cd+2].[I-].[I-]
Properties
CdI2
Molar mass 366.22 g/mol
Appearance white to pale yellow crystals
Density 5.640 g/cm3, solid
Melting point 387 °C (729 °F; 660 K)
Boiling point 742 °C (1,368 °F; 1,015 K)
787 g/L (0 °C)
847 g/L (20 °C)
1250 g/L (100 °C)
Solubility soluble in ethanol, acetone, ether and ammonia
-117.2·10−6 cm3/mol
Structure
Trigonal, hP3, space group P3m1, No. 164
octahedral
Hazards
GHS labelling:
Danger
H301, H331, H351, H373, H410
P260, P280, P301+P330+P331, P304+P340, P310, P311, P403+P233
NFPA 704 (fire diamond)
3
0
0
NIOSH (US health exposure limits):
PEL (Permissible)
[1910.1027] TWA 0.005 mg/m3 (as Cd)
REL (Recommended)
Ca
IDLH (Immediate danger)
Ca [9 mg/m3 (as Cd)]
Related compounds
Other anions
cadmium fluoride
cadmium chloride
cadmium bromide
Other cations
zinc iodide
mercury(II) iodide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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