Terbium(IV) fluoride

Terbium(IV) fluoride is an inorganic compound with a chemical formula TbF4. It is a white solid that is a strong oxidizer. It is also a strong fluorinating agent, emitting relatively pure atomic fluorine when heated, rather than the mixture of fluoride vapors emitted from cobalt(III) fluoride or cerium(IV) fluoride. It can be produced by the reaction between very pure terbium(III) fluoride and xenon difluoride, chlorine trifluoride or fluorine gas:

2 TbF3 + F2 → 2 TbF4
Terbium(IV) fluoride
Names
Other names
terbium tetrafluoride
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/4FH.Tb/h4*1H;/q;;;;+4/p-4
    Key: XWMJNWMCMQWTCG-UHFFFAOYSA-J
  • [F-].[F-].[Tb+4].[F-].[F-]
Properties
TbF4
Appearance white solid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
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