Stannane

Stannane /ˈstænn/ or tin hydride is an inorganic compound with the chemical formula SnH4. It is a colourless gas and the tin analogue of methane. Stannane can be prepared by the reaction of SnCl4 and Li[AlH4].

SnCl4 + Li[AlH4] → SnH4 + LiCl + AlCl3
Stannane
  Tin, Sn
  Hydrogen, H
Names
IUPAC name
Stannane
Other names
tin tetrahydride
tin hydride
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
  • InChI=1S/Sn.4H Y
    Key: KXCAEQNNTZANTK-UHFFFAOYSA-N Y
  • InChI=1/Sn.4H/rH4Sn/h1H4
    Key: KXCAEQNNTZANTK-GVMKXMNPAM
  • [Sn]
Properties
SnH4
Molar mass 122.71 g/mol
Appearance colourless gas
Density 5.4 g dm−3, gas
Melting point −146 °C (−231 °F; 127 K)
Boiling point −52 °C (−62 °F; 221 K)
Structure
Tetrahedral
0 D
Related compounds
Related organotins
tributylstannane (Bu3SnH)
Related compounds
Methane
Silane
Germane
Plumbane
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Stannane decomposes slowly at room temperature to give metallic tin and hydrogen and ignites on contact with air.

Variants of stannane can be found as a highly toxic, gaseous, inorganic metal hydrides and group 14 hydrides.

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