Sodium nitride

Sodium nitride is the inorganic compound with the chemical formula Na3N. In contrast to lithium nitride and some other nitrides, sodium nitride is an extremely unstable alkali metal nitride. It can be generated by combining atomic beams of sodium and nitrogen deposited onto a low-temperature sapphire substrate. It readily decomposes into its elements:

Sodium nitride
Names
IUPAC name
Sodium nitride
Identifiers
3D model (JSmol)
ECHA InfoCard 100.032.017
EC Number
  • 235-232-3
  • InChI=1/3Na.N
    Key: ZOULLXMSYSKRPG-UHFFFAOYNA-N
  • [Na]N([Na])[Na]
  • [Na+].[Na+].[Na+].[N-3]
  • [Na+].[Na][N-][Na]
Properties
Na3N
Molar mass 82.976 g/mol
Appearance reddish brown or dark blue solid
Melting point 87 °C (189 °F; 360 K) (decomposes)
reacts
Structure
Cubic, cP4
Pm3m
Thermochemistry
-151 J/mol
Related compounds
Other anions
Sodium amide
Sodium imide
Other cations
Lithium nitride
Potassium nitride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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