Lithium nitride

Lithium nitride is a compound with the formula Li3N. It is the only stable alkali metal nitride. The solid has a reddish-pink color and high melting point.

Lithium nitride

__ Li+     __ N3−

Crystal structure of lithium nitride.
Names
Preferred IUPAC name
Lithium nitride
Other names
Trilithium nitride
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.043.144
EC Number
  • 247-475-2
1156
  • InChI=1S/3Li.N
    Key: IDBFBDSKYCUNPW-UHFFFAOYSA-N
  • InChI=1S/3Li.N/q;;+1;-1
    Key: AJUFTLIHDBAQOK-UHFFFAOYSA-N
  • [Li]N([Li])[Li]
  • [Li+].[Li][N-][Li]
Properties
Li3N
Molar mass 34.83 g/mol
Appearance red, purple solid
Density 1.270 g/cm3
Melting point 813 °C (1,495 °F; 1,086 K)
reacts
log P 3.24
Structure
see text
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
reacts with water to release ammonia
GHS labelling:
Danger
H260, H314
P223, P231+P232, P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P335+P334, P363, P370+P378, P402+P404, P405, P501
NFPA 704 (fire diamond)
0
2
Related compounds
Other anions
Lithium oxide
Other cations
Sodium nitride
Potassium nitride
Related compounds
Lithium amide
Lithium imide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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