Sodium chlorate
Sodium chlorate is an inorganic compound with the chemical formula NaClO3. It is a white crystalline powder that is readily soluble in water. It is hygroscopic. It decomposes above 300 °C to release oxygen and leaves sodium chloride. Several hundred million tons are produced annually, mainly for applications in bleaching pulp to produce high brightness paper.
Unit cell of sodium chlorate | |
Names | |
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IUPAC name
Sodium chlorate | |
Other names
Sodium chlorate(V) | |
Identifiers | |
3D model (JSmol) |
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ChEBI | |
ChemSpider | |
ECHA InfoCard | 100.028.989 |
EC Number |
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KEGG | |
MeSH | Sodium+chlorate |
PubChem CID |
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RTECS number |
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UNII | |
UN number | 1495, 2428 |
CompTox Dashboard (EPA) |
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Properties | |
NaClO3 | |
Molar mass | 106.44 g mol−1 |
Appearance | Colorless or white solid, hygroscopic |
Odor | Odorless |
Density | 2.49 g/cm3 (15 °C) 2.54 g/cm3 (20.2 °C) |
Melting point | 248–261 °C (478–502 °F; 521–534 K) |
Boiling point | 300–400 °C (572–752 °F; 573–673 K) decomposes |
79 g/100 mL (0 °C) 89 g/100 mL (10 °C) 105.7 g/100 mL (25 °C) 125 g/100 mL (40 °C) 220.4 g/100 mL (100 °C) | |
Solubility | Soluble in glycerol, hydrazine, methanol Slightly soluble in ethanol, ammonia |
Solubility in acetone | Sparingly soluble |
Solubility in glycerol | 20 g/100 g (15.5 °C) |
Solubility in ethanol | 14.7 g/100 g |
Vapor pressure | <0.35 mPa |
−34.7·10−6 cm3/mol | |
Refractive index (nD) |
1.515 (20 °C) |
Structure | |
cubic | |
P213 | |
a = 6.57584 Å | |
Formula units (Z) |
4 |
Thermochemistry | |
Heat capacity (C) |
104.6 J/mol·K |
Std molar entropy (S⦵298) |
129.7 J/mol·K |
Std enthalpy of formation (ΔfH⦵298) |
-365.4 kJ/mol |
Gibbs free energy (ΔfG⦵) |
-275 kJ/mol |
Hazards | |
GHS labelling: | |
Danger | |
H271, H302, H411 | |
P220, P273 | |
NFPA 704 (fire diamond) | |
Flash point | Non-flammable |
Lethal dose or concentration (LD, LC): | |
LD50 (median dose) |
600 mg/kg (rats, oral) 700 mg/kg (dogs, oral) |
Safety data sheet (SDS) | ICSC 1117 |
Related compounds | |
Other anions |
Sodium chloride Sodium hypochlorite Sodium chlorite Sodium perchlorate Sodium bromate Sodium iodate |
Other cations |
Ammonium chlorate Potassium chlorate Barium chlorate |
Related compounds |
Chloric acid |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references |
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