Sodium chlorate

Sodium chlorate is an inorganic compound with the chemical formula NaClO3. It is a white crystalline powder that is readily soluble in water. It is hygroscopic. It decomposes above 300 °C to release oxygen and leaves sodium chloride. Several hundred million tons are produced annually, mainly for applications in bleaching pulp to produce high brightness paper.

Sodium chlorate

Unit cell of sodium chlorate
Names
IUPAC name
Sodium chlorate
Other names
Sodium chlorate(V)
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.028.989
EC Number
  • 231-887-4
KEGG
MeSH Sodium+chlorate
RTECS number
  • FO0525000
UNII
UN number 1495, 2428
  • InChI=1S/ClHO3.Na/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1 Y
    Key: YZHUMGUJCQRKBT-UHFFFAOYSA-M Y
  • InChI=1S/ClHO3.Na/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1
    Key: YZHUMGUJCQRKBT-UHFFFAOYSA-M
  • InChI=1/ClHO3.Na/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1
    Key: YZHUMGUJCQRKBT-REWHXWOFAH
  • [Na+].[O-]Cl(=O)=O
Properties
NaClO3
Molar mass 106.44 g mol−1
Appearance Colorless or white solid, hygroscopic
Odor Odorless
Density 2.49 g/cm3 (15 °C)
2.54 g/cm3 (20.2 °C)
Melting point 248–261 °C (478–502 °F; 521–534 K)
Boiling point 300–400 °C (572–752 °F; 573–673 K)
decomposes
79 g/100 mL (0 °C)
89 g/100 mL (10 °C)
105.7 g/100 mL (25 °C)
125 g/100 mL (40 °C)
220.4 g/100 mL (100 °C)
Solubility Soluble in glycerol, hydrazine, methanol
Slightly soluble in ethanol, ammonia
Solubility in acetone Sparingly soluble
Solubility in glycerol 20 g/100 g (15.5 °C)
Solubility in ethanol 14.7 g/100 g
Vapor pressure <0.35 mPa
34.7·10−6 cm3/mol
1.515 (20 °C)
Structure
cubic
P213
a = 6.57584 Å
4
Thermochemistry
104.6 J/mol·K
129.7 J/mol·K
-365.4 kJ/mol
-275 kJ/mol
Hazards
GHS labelling:
Danger
H271, H302, H411
P220, P273
NFPA 704 (fire diamond)
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
600 mg/kg (rats, oral)
700 mg/kg (dogs, oral)
Safety data sheet (SDS) ICSC 1117
Related compounds
Other anions
Sodium chloride
Sodium hypochlorite
Sodium chlorite
Sodium perchlorate
Sodium bromate
Sodium iodate
Other cations
Ammonium chlorate
Potassium chlorate
Barium chlorate
Related compounds
Chloric acid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references
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