Selenium oxydichloride

Selenium oxydichloride is the inorganic compound with the formula SeOCl2. It is a colorless liquid. With a high dielectric constant (55) and high specific conductance, it is an attractive solvent. Structurally, it is a close chemical relative of thionyl chloride SOCl2, being a pyramidal molecule.

Selenium oxydichloride
Names
IUPAC name
Selenium oxychloride
Other names
Seleninyl chloride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.313
EC Number
  • 232-244-0
RTECS number
  • VS7000000
UNII
  • InChI=1S/Cl2OSe/c1-4(2)3 N
    Key: LIRMPIXWGWLNND-UHFFFAOYSA-N N
  • InChI=1/Cl2OSe/c1-4(2)3
    Key: LIRMPIXWGWLNND-UHFFFAOYAX
  • O=[Se](Cl)Cl
Properties
SeOCl2
Molar mass 165.87 g/mol
Appearance colorless liquid
Density 2.43 g/cm3, liquid
Melting point 10.9 °C (51.6 °F; 284.0 K)
Boiling point 177.2 °C (351.0 °F; 450.3 K)
1.651 (20 °C)
Structure
trigonal pyramidal
Hazards
GHS labelling:
Warning
H301, H314, H331, H373, H410
P260, P261, P264, P270, P271, P273, P280, P301+P310, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P311, P314, P321, P330, P363, P391, P403+P233, P405, P501
NFPA 704 (fire diamond)
3
0
1
Lethal dose or concentration (LD, LC):
2 mg/kg (rabbit, dermal)
Related compounds
Related compounds
SOCl2, POCl3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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