Schweizer's reagent

Schweizer's reagent is the metal ammine complex with the formula [Cu(NH3)4(H2O)2](OH)2. This deep-blue compound is used in purifying cellulose.

Schweizer's reagent

Aqueous solution of Schweizer's reagent
Names
Other names
Cuoxam, Schweitzer's reagent
Identifiers
ChemSpider
ECHA InfoCard 100.037.720
EC Number
  • 241-508-4
UNII
Properties
[Cu(NH3)4(H2O)2](OH)2
Appearance blue solid
Melting point decomposes
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

It is prepared by dissolving copper(II) hydroxide in a solution of ammonia.

It forms an azure solution. Evaporation of these solutions leaves light blue residue of copper hydroxide, reflecting the lability of the copper-ammonia bonding. If conducted under a stream of ammonia, then deep blue needle-like crystals of the tetrammine form. In presence of oxygen, concentrated solutions give rise to nitrites Cu(NO2)2(NH3)n. The nitrite results from oxidation of the ammonia.

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