Samarium(II) iodide

Samarium(II) iodide is an inorganic compound with the formula SmI2. When employed as a solution for organic synthesis, it is known as Kagan's reagent. SmI2 is a green solid and solutions are green as well. It is a strong one-electron reducing agent that is used in organic synthesis.

Samarium(II) iodide
Names
IUPAC name
samarium(II) iodide
Other names
samarium diiodide
Identifiers
3D model (JSmol)
ChemSpider
UNII
  • InChI=1S/2HI.Sm/h2*1H;/q;;+2/p-2 Y
    Key: UAWABSHMGXMCRK-UHFFFAOYSA-L Y
  • InChI=1/2HI.Sm/h2*1H;/q;;+2/p-2
    Key: UAWABSHMGXMCRK-NUQVWONBAD
  • I[Sm]I
Properties
SmI2
Molar mass 404.16 g/mol
Appearance green solid
Melting point 520 °C (968 °F; 793 K)
Hazards
Flash point Non-flammable
Related compounds
Other anions
Samarium(II) chloride
Samarium(II) bromide
Other cations
Samarium(III) iodide
Europium(II) iodide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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