Samarium(II) chloride

Samarium(II) chloride (SmCl2) is a chemical compound, used as a radical generating agent in the ketone-mediated intraannulation reaction.

Samarium(II) chloride
Names
IUPAC name
Samarium(II) chloride
Other names
Samarium dichloride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.034.196
EC Number
  • 237-631-8
  • InChI=1S/2ClH.Sm/h2*1H;/q;;+2/p-2 Y
    Key: VPRJMFJPKMESHB-UHFFFAOYSA-L Y
  • InChI=1/2ClH.Sm/h2*1H;/q;;+2/p-2
    Key: VPRJMFJPKMESHB-NUQVWONBAS
  • Cl[Sm]Cl
Properties
SmCl2
Molar mass 221.27 g/mol
Appearance dark brown crystals
Density 3.69 g/cm3, solid
Melting point 855 °C (1,571 °F; 1,128 K)
Boiling point 1,310 °C (2,390 °F; 1,580 K)
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Structure
Orthorhombic
Pbnm, No. 62
Related compounds
Other anions
 Samarium(II) bromide
Samarium(II) iodide
Other cations
 Samarium(III) chloride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references
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