Potassium nitrate

Potassium nitrate is a chemical compound with a sharp, salty, bitter taste and the chemical formula KNO
3
. It is an ionic salt of potassium ions K+ and nitrate ions NO3, and is therefore an alkali metal nitrate. It occurs in nature as a mineral, niter (or nitre in the UK). It is a source of nitrogen, and nitrogen was named after niter. Potassium nitrate is one of several nitrogen-containing compounds collectively referred to as saltpeter (or saltpetre in the UK).

Potassium nitrate
Names
IUPAC name
Potassium nitrate
Other names
Saltpeter
Saltpetre
Nitrate of potash
Identifiers
3D model (JSmol)
ChEMBL
ChemSpider
ECHA InfoCard 100.028.926
EC Number
  • 231-818-8
E number E252 (preservatives)
KEGG
RTECS number
  • TT3700000
UNII
UN number 1486
  • InChI=1S/K.NO3/c;2-1(3)4/q+1;-1 Y
    Key: FGIUAXJPYTZDNR-UHFFFAOYSA-N Y
  • InChI=1/K.NO3/c;2-1(3)4/q+1;-1
    Key: FGIUAXJPYTZDNR-UHFFFAOYAM
  • [K+].[O-][N+]([O-])=O
Properties
KNO3
Molar mass 101.1032 g/mol
Appearance white solid
Odor odorless
Density 2.109 g/cm3 (16 °C)
Melting point 334 °C (633 °F; 607 K)
Boiling point 400 °C (752 °F; 673 K) (decomposes)
133 g/1000 g water (0 °C)
316 g/1000 g water (20 °C)
383 g/1000 g water (25 °C)
2439 g/1000 g water (100 °C)
Solubility slightly soluble in ethanol
soluble in glycerol, ammonia
Basicity (pKb) 15.3
−33.7·10−6 cm3/mol
1.335, 1.5056, 1.5604
Structure
Orthorhombic, Aragonite
Thermochemistry
95.06 J/mol K
-494.00 kJ/mol
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Oxidant, harmful if swallowed, inhaled, or absorbed on skin. Causes irritation to skin and eye area.
GHS labelling:
H272, H315, H319, H335
P102, P210, P220, P221, P280
NFPA 704 (fire diamond)
Flash point non-flammable (oxidizer)
Lethal dose or concentration (LD, LC):
1901 mg/kg (oral, rabbit)
3750 mg/kg (oral, rat)
Safety data sheet (SDS) ICSC 0184
Related compounds
Other anions
Potassium nitrite
Other cations
Lithium nitrate
Sodium nitrate
Rubidium nitrate
Caesium nitrate
Related compounds
Potassium sulfate
Potassium chloride
Supplementary data page
Potassium nitrate (data page)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Major uses of potassium nitrate are in fertilizers, tree stump removal, rocket propellants and fireworks. It is one of the major constituents of gunpowder (black powder). In processed meats, potassium nitrate reacts with hemoglobin and myoglobin generating a red color.

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