Polydymite

Polydymite, Ni2+Ni23+S4, is a supergene thiospinel sulfide mineral associated with the weathering of primary pentlandite nickel sulfide.

Polydymite
General
CategorySulfide mineral
Thiospinel group
Spinel structural group
Formula
(repeating unit)
Ni3S4
IMA symbolPld
Strunz classification2.DA.05
Crystal systemCubic
Crystal classHexoctahedral (m3m)
H-M symbol: (4/m 3 2/m)
Space groupFd3m
Unit cella = 9.48 Å; Z = 8
Identification
ColorPale to steel-gray
Crystal habitAs octahedral crystals, massive, granular to compact
TwinningTwinning on {111}
CleavageIndistinct on {001}
FractureConchoidal to uneven
Mohs scale hardness4.5 – 5.5
LusterMetallic
StreakBlack gray
DiaphaneityOpaque
Specific gravity4.5 – 4.8
Alters toTarnishes to copper-red
References

Polydymite crystallises in the isometric system, with a hardness of 4.5 to 5.5 and a specific gravity of about 4, is dark violet gray to copper-red, often with verdigris and patina from associated copper and arsenic sulfides, and is typically in amorphous to massive infill of lower saprolite ultramafic lithologies.

Polydymite is the nickel equivalent of violarite and in many cases these two minerals are formed together, potentially in solid solution.

Common contaminants of polydymite are cobalt and iron. Polydymite forms a series with linnaeite, Co+2Co+32S4.

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