Pentlandite

Pentlandite is an ironnickel sulfide with the chemical formula (Fe,Ni)9S8. Pentlandite has a narrow variation range in nickel to iron ratios (Ni:Fe), but it is usually described as 1:1. In some cases, this ratio is skewed by the presence of pyrrhotite inclusions. It also contains minor cobalt, usually at low levels as a fraction of weight.

Pentlandite
3.1 × 2.6 cm mass of pentlandite with some pyrrhotite
General
CategorySulfide mineral
Formula
(repeating unit)
iron nickel sulfide: (Fe,Ni)9S8
IMA symbolPn
Strunz classification2.BB.15a
Dana classification2.7.1.1
Crystal systemIsometric
Crystal classHexoctahedral (m3m)
H-M symbol: (4/m 3 2/m)
Space groupFm3m
Unit cella = 9.928 Å, Z = 4
Identification
Formula mass771.94 g/mol
ColorYellowish bronze
Crystal habitHexoctahedral rare; massive to granular
CleavageAbsent – octahedral parting on {111}
FractureConchoidal
TenacityBrittle
Mohs scale hardness3.5–4
LusterMetallic
StreakLight bronze-brown
Greenish black
DiaphaneityOpaque
Specific gravity4.6–5.0
Density4.6–5 g/cm3
Fusibility1.5–2
Other characteristicsBecomes magnetic upon heating
References

Pentlandite forms isometric crystals, but it is normally found in massive granular aggregates. It is brittle with a hardness of 3.5–4 and specific gravity of 4.6–5.0 and is non-magnetic. It has a yellowish bronze color and a metallic luster.

Pentlandite is found in abundance within ultramafic rocks, making it one of the most important sources of mined nickel. It also occasionally occurs within mantle xenoliths and "black smoker" hydrothermal vents.

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