Periodic acid

Periodic acid (/ˌpɜːrˈɒdɪk/ per-eye-OD-ik) is the highest oxoacid of iodine, in which the iodine exists in oxidation state +7. It can exist in two forms: orthoperiodic acid, with the chemical formula H5IO6, and metaperiodic acid, which has the formula HIO4.

Periodic acid
Orthoperiodic acid
Metaperiodic acid

HIO4·2H2O
Names
Other names
  • Paraperiodic acid
  • Iodic(VII) acid
  • Hydrogen periodate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.839
EC Number
  • 236-585-6
UNII
UN number UN3085
  • (orthoperiodic): InChI=I=1S/H5IO6/c2-1(3,4,5,6)7/h(H5,2,3,4,5,6,7)
    Key: TWLXDPFBEPBAQB-UHFFFAOYSA-N
  • (metaperiodic): InChI=1/HIO4/c2-1(3,4)5/h(H,2,3,4,5)
    Key: KHIWWQKSHDUIBK-UHFFFAOYAH
  • (orthoperiodic): OI(=O)(O)(O)(O)O
  • (metaperiodic): O[I+3]([O-])([O-])[O-]
Properties
HIO4 (metaperiodic)
H5IO6 (orthoperiodic)
Molar mass 190.91 g/mol (HIO4)
227.941 g/mol (H5IO6)
Appearance Colourless crystals
Melting point 128.5 °C (263.3 °F; 401.6 K)
Solubility soluble in water, alcohols
Conjugate base Periodate
Hazards
GHS labelling:
Danger
H271, H314, H372, H400
P210, P260, P273, P303+P361+P353, P305+P351+P338
NFPA 704 (fire diamond)
Safety data sheet (SDS) External MSDS
Related compounds
Other anions
Other cations
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Periodic acid was discovered by Heinrich Gustav Magnus and C. F. Ammermüller in 1833.

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