Perchloric acid

Perchloric acid is a mineral acid with the formula HClO4. Usually found as an aqueous solution, this colorless compound is a stronger acid than sulfuric acid, nitric acid and hydrochloric acid. It is a powerful oxidizer when hot, but aqueous solutions up to approximately 70% by weight at room temperature are generally safe, only showing strong acid features and no oxidizing properties. Perchloric acid is useful for preparing perchlorate salts, especially ammonium perchlorate, an important rocket fuel component. Perchloric acid is dangerously corrosive and readily forms potentially explosive mixtures.

Perchloric acid
Names
Systematic IUPAC name
Perchloric acid
Other names
Hyperchloric acid
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.028.648
EC Number
  • 231-512-4
RTECS number
  • SC7500000
UNII
UN number 1873
  • InChI=1S/ClHO4/c2-1(3,4)5/h(H,2,3,4,5) Y
    Key: VLTRZXGMWDSKGL-UHFFFAOYSA-N Y
  • InChI=1/ClHO4/c2-1(3,4)5/h(H,2,3,4,5)
    Key: VLTRZXGMWDSKGL-UHFFFAOYAD
  • O[Cl+3]([O-])([O-])[O-]
Properties
HClO4
Molar mass 100.46 g/mol
Appearance colorless liquid
Odor odorless
Density 1.768 g/cm3
Melting point −17 °C (1 °F; 256 K) (72% aqueous solution)
−112 °C (anhydrous)
Boiling point 203 °C (397 °F; 476 K) (azeotrope)
Miscible
Acidity (pKa) −15.2 (±2.0); ≈ −10
Conjugate base Perchlorate
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Powerful oxidizer, highly corrosive
GHS labelling:
Danger
H271, H290, H302, H314, H373
P210, P280, P303+P361+P353, P304+P340, P305+P351+P338, P310, P371, P375, P380
NFPA 704 (fire diamond)
Flash point Non-flammable
Safety data sheet (SDS) ICSC 1006
Related compounds
Related compounds
Hydrochloric acid
Hypochlorous acid
Chlorous acid
Chloric acid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is YN ?)
Infobox references
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