Silver(I) selenide

Silver selenide (Ag2Se) is the reaction product formed when selenium toning analog silver gelatine photo papers in photographic print toning. The selenium toner contains sodium selenite (Na2SeO3) as one of its active ingredients, which is the source of the selenide (Se2−) anion combining with the silver in the toning process.

Silver(I) selenide
Names
IUPAC name
Silver(I) selenide
Other names
Naumannite
Argentous selenide
Identifiers
3D model (JSmol)
ECHA InfoCard 100.013.727
UNII
  • InChI=1S/2Ag.Se
    Key: GNWCVDGUVZRYLC-UHFFFAOYSA-N
  • [Se].[Ag].[Ag]
Properties
Ag2Se
Molar mass 294.7 g/mol
Density 8.216 g/cm3, solid
Melting point 896.85 °C (1,646.33 °F; 1,170.00 K)
insoluble
Band gap 0.15 eV
Structure
orthorhombic, oP12
P212121, No. 19
Thermochemistry
Enthalpy of fusion fHfus)
56.9 J/g
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

It is found in nature as the mineral naumannite, a comparatively rare silver mineral which has nevertheless become recognized as important silver compound in some low-sulfur silver ores from mines in Nevada and Idaho.

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