Ferrocenium tetrafluoroborate
Ferrocenium tetrafluoroborate is an organometallic compound with the formula [Fe(C5H5)2]BF4. This salt is composed of the cation [Fe(C5H5)2]+ and the tetrafluoroborate anion (BF−
4). The related hexafluorophosphate is also a popular reagent with similar properties. The ferrocenium cation is often abbreviated Fc+ or Cp2Fe+. The salt is deep blue in color and paramagnetic.
Ferrocenium salts are sometimes used as one-electron oxidizing agents, and the reduced product, ferrocene, is inert and readily separated from ionic products. The ferrocene–ferrocenium couple is often used as a reference in electrochemistry. The standard potential of ferrocene-ferrocenium is dependent on specific electrochemical conditions.
Names | |
---|---|
IUPAC name
Ferrocenium tetrafluoroborate | |
Identifiers | |
3D model (JSmol) |
|
ChemSpider | |
ECHA InfoCard | 100.156.161 |
EC Number |
|
PubChem CID |
|
CompTox Dashboard (EPA) |
|
| |
Properties | |
C10H10BFeF4 | |
Molar mass | 272.84 g/mol |
Appearance | dark blue powder |
Melting point | 178 °C (352 °F; 451 K) (decomposes) |
Solubility in acetonitrile | Soluble |
Hazards | |
GHS labelling: | |
Danger | |
H314 | |
P280, P305+P351+P338, P310 | |
Safety data sheet (SDS) | External MSDS |
Related compounds | |
Related compounds |
Ferrocene |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references |
This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.