Ferrocenium tetrafluoroborate

Ferrocenium tetrafluoroborate is an organometallic compound with the formula [Fe(C5H5)2]BF4. This salt is composed of the cation [Fe(C5H5)2]+ and the tetrafluoroborate anion (BF
4
). The related hexafluorophosphate is also a popular reagent with similar properties. The ferrocenium cation is often abbreviated Fc+ or Cp2Fe+. The salt is deep blue in color and paramagnetic. Ferrocenium salts are sometimes used as one-electron oxidizing agents, and the reduced product, ferrocene, is inert and readily separated from ionic products. The ferrocene–ferrocenium couple is often used as a reference in electrochemistry. The standard potential of ferrocene-ferrocenium is dependent on specific electrochemical conditions.

Ferrocenium tetrafluoroborate
Names
IUPAC name
Ferrocenium tetrafluoroborate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.156.161
EC Number
  • 627-836-4
  • C1=C[CH-]C=C1.[Fe+3].C2=C[CH-]C=C2.F[B-](F)(F)F
Properties
C10H10BFeF4
Molar mass 272.84 g/mol
Appearance dark blue powder
Melting point 178 °C (352 °F; 451 K) (decomposes)
Solubility in acetonitrile Soluble
Hazards
GHS labelling:
Danger
H314
P280, P305+P351+P338, P310
Safety data sheet (SDS) External MSDS
Related compounds
Related compounds
Ferrocene
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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