Hexafluorophosphate

Hexafluorophosphate is an anion with chemical formula of [PF6]. It is an octahedral species that imparts no color to its salts. [PF6] is isoelectronic with sulfur hexafluoride, SF6, and the hexafluorosilicate dianion, [SiF6]2−, and hexafluoroantimonate [SbF6]. In this anion, phosphorus has a valence of 5. Being poorly nucleophilic, hexafluorophosphate is classified as a non-coordinating anion.

Hexafluorophosphate
Names
IUPAC name
Hexafluorophosphate
Systematic IUPAC name
Hexafluoro-λ5-phosphanuide (substitutive)
Hexafluoridophosphate(1-) (additive)
Other names
Hexafluorophosphate(V)
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.111.656
EC Number
  • 605-543-2
2704
UNII
  • InChI=1S/F6P/c1-7(2,3,4,5)6/q-1 Y
    Key: LJQLCJWAZJINEB-UHFFFAOYSA-N Y
  • F[P-](F)(F)(F)(F)F
Properties
[PF6]
Molar mass 144.964181 g/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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