Dichlorine trioxide

Dichlorine trioxide, Cl2O3, is a chlorine oxide. It is a dark brown solid discovered in 1967 which is explosive even below 0 °C. It is formed by the low-temperature photolysis of ClO2 and is formed along with Cl2O6, Cl2 and O2. Its structure is believed to be OClClO2 with possible isomers such as ClOClO2. The isomer having a structure of OCl–O–ClO would be the theoretical anhydride of chlorous acid.

Dichlorine trioxide
Names
IUPAC name
dichlorine trioxide
Other names
chlorine trioxide
chlorine chlorate
chlorine(I,V) oxide
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/Cl2O3/c1-5-2(3)4 Y
    Key: SAUMVKNLVQDHMJ-UHFFFAOYSA-N Y
  • InChI=1/Cl2O3/c1-5-2(3)4
    Key: SAUMVKNLVQDHMJ-UHFFFAOYAS
  • ClOCl(=O)=O
Properties
Cl2O3
Molar mass 118.903 g/mol
Appearance dark brown solid
Melting point explodes below 0 °C
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references
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