Chlordane

Chlordane, or chlordan, is an organochlorine compound that was used as a pesticide. It is a white solid. In the United States, chlordane was used for termite-treatment of approximately 30 million homes until it was banned in 1988. Chlordane was banned 10 years earlier for food crops like corn and citrus, and on lawns and domestic gardens.

Chlordane
cis-chlordane (α-chlordane)
trans-chlordane (γ-chlordane, beta-chlordane)
cis-chlordane
trans-chlordane
Names
Systematic IUPAC name
1,2,4,5,6,7,8,8-Octachloro-3a,4,7,7a-tetrahydro-4,7-methanoindane
Other names
Chlordan; Chlordano; Ortho; Octachloro-4,7-methanohydroindane
Identifiers
ECHA InfoCard 100.000.317
KEGG
UNII
Properties
C10H6Cl8
Molar mass 409.76 g·mol−1
Appearance White solid
Odor Slightly pungent, chlorine-like
Density 1.59 g/cm3
Melting point 102–106 °C (216–223 °F; 375–379 K)
Boiling point decomposes
0.0001% (20°C)
1.565
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
potential occupational carcinogen
GHS labelling:
Danger
H301, H311, H351, H410
P201, P273, P280, P301+P310+P330, P302+P352+P312
Flash point 107 °C (225 °F; 380 K) (open cup)
Explosive limits 0.7–5%
Lethal dose or concentration (LD, LC):
590 mg/kg (rat, oral)
100 mg/kg (rabbit, oral)
430 mg/kg (mouse, oral)
300 mg/kg (rabbit, oral)
145 mg/kg (mouse, oral)
1720 mg/kg (hamster, oral)
200 mg/kg (rat, oral)
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 0.5 mg/m3 [skin]
REL (Recommended)
Ca TWA 0.5 mg/m3 [skin]
IDLH (Immediate danger)
100 mg/m3
Safety data sheet (SDS) Chlordane (technical mixture)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Like other chlorinated cyclodiene insecticides, chlordane is classified as an organic pollutant hazardous for human health. It is resistant to degradation in the environment and in humans/animals and readily accumulates in lipids (fats) of humans and animals. Exposure to the compound has been linked to cancers, diabetes, and neurological disorders.

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