Bromoiodomethane

Bromoiodomethane is a halomethane with the formula BrCH2I. It is a colorless liquid, although older samples appear yellow. The compound has been investigated as a reagent for cyclopropanation by the Simmons-Smith reaction, but diiodomethane and chloroiodomethane are preferred. It also occurs naturally as the result of microbial action.

Bromoiodomethane
Names
Preferred IUPAC name
Bromo(iodo)methane
Other names
  • Bromoiodomethane
  • Bromomethyl iodide
  • Iodobromomethane
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.156.567
  • InChI=1S/CH2BrI/c2-1-3/h1H2 Y
    Key: TUDWMIUPYRKEFN-UHFFFAOYSA-N Y
  • BrCI
Properties
CH2BrI
Molar mass 220.835 g·mol−1
Appearance Colourless liquid
Density 2.93 g mL−1
Melting point 1 °C; 34 °F; 274 K
Boiling point 138 to 141 °C (280 to 286 °F; 411 to 414 K)
1.6382
Hazards
GHS labelling:
Danger
H315, H318, H335
P261, P280, P305+P351+P338
Related compounds
Related alkanes
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is YN ?)
Infobox references

Its critical point is at 367.85 °C and 6.3 MPa and refractive index is 1.6382 (20 °C, D).

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