Dibromine trioxide

Dibromine trioxide is the chemical compound composed of bromine and oxygen with the formula Br2O3. It is an orange solid that is stable below 40 °C. It has the structure BrOBrO2 (bromine bromate). It was discovered at 1993. The bond angle of BrOBr is 111.7°, the bond angle of OBr=O is 103.1°, and the bond angle of O=Br=O is 107.6°. The BrOBrO2 bond length is 1.845Å, the OBrO2 bond length is 1.855Å, and the Br=O bond length is 1.612Å.

Dibromine trioxide
Names
IUPAC name
Dibromine trioxide
Other names
Bromine trioxide
Bromine bromate
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/Br2O3/c1-5-2(3)4
    Key: XLGPPSYTBHJSNE-UHFFFAOYSA-N
  • BrO[Br](=O)=O
Properties
Br2O3
Molar mass 207.806 g/mol
Appearance orange needles
Melting point decomposes around 40°C
Structure
monoclinic
P21/c
a = 1186.6 pm, b = 762.9 pm, c = 869.3 pm
α = 90°, β = 106.4°, γ = 90°
Related compounds
Other anions
Bromine dioxide
Bromine trifluoride
Bromine pentafluoride
Other cations
Oxygen difluoride
Dichlorine monoxide
Chlorine dioxide
Iodine dioxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N (what is YN ?)
Infobox references
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