The Portable Executable (PE) format, a modification of COFF, is the file format for executable binaries under the Windows operating system. The PE format is easily recognized by its "MZ DOS header" (0x4d 0x5a, "MZ" for "Mark Zbikowski").
The Portable Executable (PE) format is a file format for executable files (EXE and DLL), used in 32-bit and 64-bit versions of Windows operating systems. It is derived from the earlier coff format.
Documentation
A 2-part feature in ran in MSDN Magazine in February and March 2002 that describes the format.