If you are using sessions and reusing the Session ID for your concurrent requests, ASP.NET will queue the requests because it needs an exclusive lock on the session for each request.
Taken from http://msdn.microsoft.com/en-us/library/ms178581.aspx
Concurrent Requests and Session State
Access to ASP.NET session state is exclusive per session, which means
that if two different users make concurrent requests, access to each
separate session is granted concurrently. However, if two concurrent
requests are made for the same session (by using the same SessionID
value), the first request gets exclusive access to the session
information. The second request executes only after the first request
is finished. (The second session can also get access if the exclusive
lock on the information is freed because the first request exceeds the
lock time-out.) If the EnableSessionState value in the @ Page
directive is set to ReadOnly, a request for the read-only session
information does not result in an exclusive lock on the session data.
However, read-only requests for session data might still have to wait
for a lock set by a read-write request for session data to clear.