How to calculate the Standard Deviation on Pandas Dataframe using GroupBy in python

Question

I have this kind of Dataframe:

Tag  X
2   45.5
5   56.4
4   34.2
2   89.5
4   78.1
5   44.1
6   35.5

I would like to calculate the Standard Deviation for each object in the column 'Tag' using the .group.by function if possible. I tried this code, but it doesn't work:

Df['Std X'] = Df[['X']].groupby(Df['Tag']).std(axis=1)

Thanks for the help