In dev tools of your browser start by checking the page source. Or if you want to use inspector to assist you with CSS selectors or XPaths, first turn off javascript for that page. This allows you to work on the same content that is (hopefully) received by rvest and from the chart placeholder you can extract XPath for the <a>
element that includes data for the graph:

URL in data-link
provides parameters for the chart generator, though data
parameter happens to include not one but multiple data series, one for each meteogram chart. Each of those 14-value series are separated by :
, so we need to extract just one of those. And also the date of for the first value in series.
library(rvest)
library(stringr)
link <- read_html("https://www.ventusky.com/-14.868;-71.332")
chart_url_params <- link %>%
html_element(xpath='//*[@id="graph_rain"]/a') %>%
html_attr("data-link") %>%
# split by all separators: "&", "=", ":"
str_split('&|=|:',simplify = T)
chart_url_params[1:9]
#> [1] "rain"
#> [2] "data"
#> [3] "-1;0;0;0;5;4;4;-1;4;5;5;5;4;4"
#> [4] "17;19;19;18;16;18;19;18;17;17;12;16;15;17"
#> [5] "0.1;0;0;1;10.1;0;0;0;0;0.1;9.9;0.1;10.2;0.6"
#> [6] "36;32;36;40;32;40;40;22;25;25;14;18;25;29"
#> [7] "0;0;0;0;0;0;0;0;0;0;0;0;0;0"
#> [8] "time"
#> [9] "1666418400"
# 9: starting date as Unix timestamp
# 5: precip. data, identifyed by checking rendered chart
start_date <- as.Date(as.POSIXct(as.numeric(chart_url_params[9]), origin="1970-01-01"))
precip <- chart_url_params[5] %>%
str_split(";", simplify = T) %>%
as.numeric()
tibble::tibble(
date = seq(from = start_date, by = "day", along.with=precip),
precip = precip)
Result:
#> # A tibble: 14 × 2
#> date precip
#> <date> <dbl>
#> 1 2022-10-22 0.1
#> 2 2022-10-23 0
#> 3 2022-10-24 0
#> 4 2022-10-25 1
#> 5 2022-10-26 10.1
#> 6 2022-10-27 0
#> 7 2022-10-28 0
#> 8 2022-10-29 0
#> 9 2022-10-30 0
#> 10 2022-10-31 0.1
#> 11 2022-11-01 9.9
#> 12 2022-11-02 0.1
#> 13 2022-11-03 10.2
#> 14 2022-11-04 0.6
Created on 2022-10-22 with reprex v2.0.2