Use the ItemDataBound event of the Repeater, like this:
protected void rep_UnAssignComps_ItemDataBound(object sender, RepeaterItemEventArgs e)
{
DropDownList selectList = e.Item.FindControl("drp_CompPropAddress") as DropDownList;
if (selectList != null)
{
selectList.DataSource = SomeDataSource(); //your datasource
selectList.DataBind();
//selectList.DataTextField = "SomeColumn";
//selectList.DataValueField = "SomeID";
}
}
Also remember to set the DataTextField and DataValueField properties, either in the markup or in the ItemDataBound event.