I wanted to enable pooling at the Entity Framework level so that connections are reused
Entity Framework doesn't get involved at the "connections are reused" level. Pooling in that regard is a process of ADO.net forging e.g. a TCP connection to a database (which is a relatively long and resource intensive operation) and keeping it open. When your old school code like using var conn = new SqlConnection("connstr here")
calls conn.Open()
one of these already-connected connections is leased from the pool and handed to you; you do some queries and then Close (or dispose, which closes) the connection but that doesn't actually disconnect the database; it just returns the connection to the pool
As noted, EF doesn't get involved in this; it's been a thing since long before EF was invented and is active by default unless you've turned it off specifically. EF will use ADO.net connections like any other app, so it already benefits from connection pooling passively
The article youre reading is about a different set of things being pooled. Typically a DbContext is a light weight short lived thing that represents a device that forms queries to a database; you're supposed to make one, use it for a few queries and then throw it away.
It's designed for fast creation but that doesn't mean there aren't minor improvements to be had and if you've identified a situation where you need to wring every last drop of performance out of the system then EF offers a way to dispense with the typical "throw it away and make another" route of making sure you're using a fresh DbContext by providing a facility for DbContexts to be pooled, and rather than being made anew they're reset
It's probably unlikely you're in that place where pooling your contexts would make a significant difference; you're asking about enabling connection pooling but in all likelihood it'll be already enabled because you would know if you'd put "Pooling=false" in a connection string.
For more info on connection pooling, see https://learn.microsoft.com/en-us/dotnet/framework/data/adonet/sql-server-connection-pooling