You want to select the stock items and join the in totals and out totals. Aggregate to get the totals. Outer join to get items with and without transactions. Use COALESCE
to replace nulls with zeros.
select
s.barcode, s.item_name,
coalesce(si.total, 0) as amount_in,
coalesce(so.total, 0) as amount_out,
coalesce(si.total, 0) - coalesce(so.total, 0) as balance,
s.unit
from stock_items s
left join
(
select barcode, sum(amount) as total
from stock_in
group by barcode
) si on si.barcode = s.barcode
left join
(
select barcode, sum(amount) as total
from stock_out
group by barcode
) so on so.barcode = s.barcode
order by s.barcode;