first of all I'm a little bit confused why you are using a DataFrame. This is more likely being stored in a pd.Series while I would suggest storing numeric data in an numpy array. Assuming that you are having a pd.Series in front of you and you are trying to calculate the moving average between two consecutive points, there are two approaches you can follow.
zero-paddding for the last integer:
assuming circularity and taking the average between the first and the last value
Here is the expected code:
import numpy as np
import pandas as pd
data_series = pd.Series([0,0,0.76231, 0.77669,0,0,0,0,0,0,0,0,0.66772, 1.37964, 2.11833, 2.29178, 0,0,0,0,0])
np_array = np.array(data_series)
#assuming zero_padding
np_array_zero_pad = np.hstack((np_array, 0))
mvavrg_zeropad = [np.mean([np_array_zero_pad[i], np_array_zero_pad[i+1]]) for i in range(len(np_array_zero_pad)-1)]
#asssuming circularity
np_array_circ_arr = np.hstack((np_array, np_array[-1]))
np_array_circ_arr = [np.mean([np_array_circ_arr[i], np_array_circ_arr[i+1]]) for i in range(len(np_array_circ_arr)-1)]