Can multiple runbooks run simultaneously in an azure automation account? If yes, how many?
Yes, more specifically, it should be runbook jobs instead of runbooks, starting a runbook in Azure Automation creates a job, which is a single execution instance of the runbook.
And runbooks in Azure Automation can run on either an Azure sandbox or a Hybrid Runbook Worker, they have different limits, if you start your runbook in the portal, it uses Azure sandbox.
For Azure sandbox:

For Hybrid Runbook Worker:

Reference - https://learn.microsoft.com/en-us/azure/azure-resource-manager/management/azure-subscription-service-limits#automation-limits
But I see that the runbooks are queued.
The status Queued
does not mean the runbooks are waiting for the running jobs to complete, Azure Automation assigns a worker to run each job during runbook execution, they are just waiting for the worker.
Reference - https://learn.microsoft.com/en-us/azure/automation/automation-runbook-execution#job-statuses

Is there a limit for simultaneous runs?
Yes, as mentioned above, there is a limit 200
for simultaneous runs per automation account for Azure sandbox.
If yes, can it be increased?
No, it cannot be increased.