Create a union query like this:
Select ID_Jadwal, [Shift], Supervisor As Nm_Karyawan, "Supervisor" As Posisi
From YourTable
Where Supervisor Is Not Null
Union All
Select ID_Jadwal, [Shift], Printing, "Printing"
From YourTable
Where Printing Is Not Null
Union All
Select ID_Jadwal, [Shift], Tinta, "Tinta"
From YourTable
Where Tinta Is Not Null
Union All
Select ID_Jadwal, [Shift], Cylinder, "Cylinder"
From YourTable
Where Cylinder Is Not Null
Union All
Select ID_Jadwal, [Shift], Dry, "Dry"
From YourTable
Where Dry Is Not Null
Union All
Select ID_Jadwal, [Shift], Extrusion, "Extrusion"
From YourTable
Where Extrusion Is Not Null
Union All
Select ID_Jadwal, [Shift], Slitting, "Slitting"
From YourTable
Where Slitting Is Not Null
Union All
Select ID_Jadwal, [Shift], Rewind, "Rewind"
From YourTable
Where Rewind Is Not Null
Use this as source in your append query.